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Pentaerythritol tetranitrate

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Pentaerythritol tetranitrate
Skeletal formula
Ball-and-stick model
Pentaerythritol tetranitrate after crystalization from acetone
Names
Preferred IUPAC name
2,2-Bis[(nitrooxy)methyl]propane-1,3-diyl dinitrate
Other names
[3-Nitrooxy-2,2-bis(nitrooxymethyl)propyl] nitrate
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.000.987 Edit this at Wikidata
UNII
  • InChI=1S/C5H8N4O12/c10-6(11)18-1-5(2-19-7(12)13,3-20-8(14)15)4-21-9(16)17/h1-4H2 checkY
    Key: TZRXHJWUDPFEEY-UHFFFAOYSA-N checkY
  • InChI=1S/C5H8N4O12/c10-6(11)18-1-5(2-19-7(12)13,3-20-8(14)15)4-21-9(16)17/h1-4H2
  • C(C(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-])O[N+](=O)[O-]
Properties
C5H8N4O12
Molar mass 316.137 g/mol
Appearance White crystalline solid[1]
Density 1.77 g/cm3 at 20 °C
Melting point 141.3 °C (286.3 °F; 414.4 K)
Boiling point 180 °C (356 °F; 453 K) (decomposes above 150 °C (302 °F))
Explosive data
Shock sensitivity Medium
Friction sensitivity Medium
Detonation velocity 8400 m/s (density 1.7 g/cm3)
RE factor 1.66
Hazards
GHS labelling:
GHS06: Toxic GHS01: Explosive GHS08: Health hazard
Danger
H201, H241, H302, H316, H370, H373
P210, P250, P261, P264, P301+P312, P370+P380, P372, P401, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxideSpecial hazards (white): no code
2
1
3
190 °C (374 °F; 463 K)
Pharmacology
C01DA05 (WHO)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Pentaerythritol tetranitrate (PETN), also known as PENT, pentyl, PENTA (ПЕНТА, primarily in Russian), TEN (tetraeritrit nitrate), corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythritol, and is structurally very similar to nitroglycerin. Penta refers to the five carbon atoms of the neopentane skeleton. PETN is a very powerful explosive material with a relative effectiveness factor of 1.66.[2] When mixed with a plasticizer, PETN forms a plastic explosive.[3] Along with RDX it is the main ingredient of Semtex.

PETN is also used as a vasodilator drug to treat certain heart conditions, such as for management of angina.[4][5]

History

[edit]

Pentaerythritol tetranitrate was first prepared and patented in 1894 by the explosives manufacturer Rheinisch-Westfälische Sprengstoff A.G. [de] of Cologne, Germany.[6][7][8][9] The production of PETN started in 1912, when the improved method of production was patented by the German government. PETN was used by the German Military in World War I.[10][11] It was also used in the MG FF/M autocannons and many other weapon systems of the Luftwaffe in World War II.[citation needed]

Properties

[edit]

PETN is practically insoluble in water (0.01 g/100 mL at 50 °C), weakly soluble in common nonpolar solvents such as aliphatic hydrocarbons (like gasoline) or tetrachloromethane, but soluble in some other organic solvents, particularly in acetone (about 15 g/100 g of the solution at 20 °C, 55 g/100 g at 60 °C) and dimethylformamide (40 g/100 g of the solution at 40 °C, 70 g/100 g at 70 °C). It is a non-planar molecule that crystallizes in the space group P421c.[12] PETN forms eutectic mixtures with some liquid or molten aromatic nitro compounds, e.g. trinitrotoluene (TNT) or tetryl. Due to steric hindrance of the adjacent neopentyl-like moiety, PETN is resistant to attack by many chemical reagents; it does not hydrolyze in water at room temperature or in weaker alkaline aqueous solutions. Water at 100 °C or above causes hydrolysis to dinitrate; presence of 0.1% nitric acid accelerates the reaction.

The chemical stability of PETN is of interest, because of the presence of PETN in aging weapons.[13] Neutron radiation degrades PETN, producing carbon dioxide and some pentaerythritol dinitrate and trinitrate. Gamma radiation increases the thermal decomposition sensitivity of PETN, lowers melting point by few degrees Celsius, and causes swelling of the samples. Like other nitrate esters, the primary degradation mechanism is the loss of nitrogen dioxide; this reaction is autocatalytic.[citation needed] Studies were performed on thermal decomposition of PETN.[14]

In the environment, PETN undergoes biodegradation. Some bacteria denitrate PETN to trinitrate and then dinitrate, which is then further degraded.[15] PETN has low volatility and low solubility in water, and therefore has low bioavailability for most organisms. Its toxicity is relatively low, and its transdermal absorption also seems to be low. It poses a threat for aquatic organisms. It can be degraded to pentaerythritol by iron.[16]

Production

[edit]

Production is by the reaction of pentaerythritol with concentrated nitric acid to form a precipitate which can be recrystallized from acetone to give processable crystals.[17]

Variations of a method first published in US Patent 2,370,437 by Acken and Vyverberg (1945 to Du Pont) form the basis of all current commercial production.[citation needed]

PETN is manufactured by numerous manufacturers as a powder, or together with nitrocellulose and plasticizer as thin plasticized sheets (e.g. Primasheet 1000 or Detasheet). PETN residues are easily detectable in hair of people handling it.[18] The highest residue retention is on black hair; some residues remain even after washing.[19][20]

Explosive use

[edit]
Pentaerythritol tetranitrate before crystallization from acetone

The most common use of PETN is as an explosive with high brisance. It is a secondary explosive, meaning it is more difficult to detonate than primary explosives, so dropping or igniting it will typically not cause an explosion (at standard atmospheric pressure it is difficult to ignite and burns vigorously), but is more sensitive to shock and friction than other secondary explosives such as TNT or tetryl.[17][21] Under certain conditions a deflagration to detonation transition can occur, just like that of ammonium nitrate.

It is rarely used alone in military operations due to its lower stability, but is primarily used in the main charges of plastic explosives (such as C4) along with other explosives (especially RDX), booster and bursting charges of small caliber ammunition, in upper charges of detonators in some land mines and shells, as the explosive core of detonation cord.[22][23] PETN is the least stable of the common military explosives, but can be stored without significant deterioration for longer than nitroglycerin or nitrocellulose.[24]

During World War II, PETN was most importantly used in exploding-bridgewire detonators for the atomic bombs. These exploding-bridgewire detonators gave more precise detonation compared to primacord. PETN was used for these detonators because it was safer than primary explosives like lead azide: while it was sensitive, it would not detonate below a threshold amount of energy.[25] Exploding bridgewires containing PETN remain used in current nuclear weapons. In spark detonators, PETN is used to avoid the need for primary explosives; the energy needed for a successful direct initiation of PETN by an electric spark ranges between 10–60 mJ.

PETN was used in the manufacturing of pagers provided to Hezbollah. On September 17, 2024, the pagers detonated, killing 12 people and injuring thousands.[26]

Its basic explosion characteristics are:

  • Explosion energy: 5810 kJ/kg (1390 kcal/kg), so 1 kg of PETN has the energy of 1.24 kg TNT.
  • Detonation velocity: 8350 m/s (1.73 g/cm3), 7910 m/s (1.62 g/cm3), 7420 m/s (1.5 g/cm3), 8500 m/s (pressed in a steel tube)
  • Volume of gases produced: 790 dm3/kg (other value: 768 dm3/kg)
  • Explosion temperature: 4230 °C
  • Oxygen balance: −6.31 atom -g/kg
  • Melting point: 141.3 °C (pure), 140–141 °C (technical)
  • Trauzl lead block test: 523 cm3 (other values: 500 cm3 when sealed with sand, or 560 cm3 when sealed with water)
  • Critical diameter (minimal diameter of a rod that can sustain detonation propagation): 0.9 mm for PETN at 1 g/cm3, smaller for higher densities (other value: 1.5 mm)

In mixtures

[edit]

PETN is used in a number of compositions. It is a major ingredient of the Semtex plastic explosive. It is also used as a component of pentolite, a 50/50 blend with TNT. The XTX8003 extrudable explosive, used in the W68 and W76 nuclear warheads, is a mixture of 80% PETN and 20% of Sylgard 182, a silicone rubber.[27] It is often phlegmatized by addition of 5–40% of wax, or by polymers (producing polymer-bonded explosives); in this form it is used in some cannon shells up to 30 mm caliber, though it is unsuitable for higher calibers. It is also used as a component of some gun propellants and solid rocket propellants. Nonphlegmatized PETN is stored and handled with approximately 10% water content. PETN alone cannot be cast as it explosively decomposes slightly above its melting point,[citation needed][clarification needed] but it can be mixed with other explosives to form castable mixtures.

PETN can be initiated by a laser.[28] A pulse with duration of 25 nanoseconds and 0.5–4.2 joules of energy from a Q-switched ruby laser can initiate detonation of a PETN surface coated with a 100 nm thick aluminium layer in less than half of a microsecond.[citation needed]

PETN has been replaced in many applications by RDX, which is thermally more stable and has a longer shelf life.[29] PETN can be used in some ram accelerator types.[30] Replacement of the central carbon atom with silicon produces Si-PETN, which is extremely sensitive.[31][32]

Terrorist use

[edit]
Main articles: Shoe Bomber, 2009 Christmas Day bomb plot, and 2010 cargo plane bomb plot

Ten kilograms of PETN was used in the 1980 Paris synagogue bombing.

In 1983, 307 people were killed after a truck bomb filled with PETN was detonated at the Beirut barracks.

In 1983, the "Maison de France" house in Berlin was brought to a near-total collapse by the detonation of 24 kilograms (53 lb) of PETN by terrorist Johannes Weinrich.[33]

On July 17, 1996, flight TWA 800 exploded and crashed in the Atlantic Ocean. Traces of PETN were found in the wreckage.

In 1999, Alfred Heinz Reumayr used PETN as the main charge for his fourteen improvised explosive devices that he constructed in a thwarted attempt to damage the Trans-Alaska Pipeline System.

In 2001, al-Qaeda member Richard Reid, the "Shoe Bomber", used PETN in the sole of his shoe in his unsuccessful attempt to blow up American Airlines Flight 63 from Paris to Miami.[20][34] He had intended to use the solid triacetone triperoxide (TATP) as a detonator.[21]

In 2009, PETN was used in an attempt by al-Qaeda in the Arabian Peninsula to murder the Saudi Arabian Deputy Minister of Interior Prince Muhammad bin Nayef, by Saudi suicide bomber Abdullah Hassan al Asiri. The target survived and the bomber died in the blast. The PETN was hidden in the bomber's rectum, which security experts described as a novel technique.[35][36][37]

On 25 December 2009, PETN was found in the underwear of Umar Farouk Abdulmutallab, the "Underwear bomber", a Nigerian with links to al-Qaeda in the Arabian Peninsula.[38] According to US law enforcement officials,[39] he had attempted to blow up Northwest Airlines Flight 253 while approaching Detroit from Amsterdam.[40] Abdulmutallab had tried, unsuccessfully, to detonate approximately 80 grams (2.8 oz) of PETN sewn into his underwear by adding liquid from a syringe;[41] however, only a small fire resulted.[21]

In the al-Qaeda in the Arabian Peninsula October 2010 cargo plane bomb plot, two PETN-filled printer cartridges were found at East Midlands Airport and in Dubai on flights bound for the US on an intelligence tip. Both packages contained sophisticated bombs concealed in computer printer cartridges filled with PETN.[42][43] The bomb found in England contained 400 grams (14 oz) of PETN, and the one found in Dubai contained 300 grams (11 oz) of PETN.[43] Hans Michels, professor of safety engineering at University College London, told a newspaper that 6 grams (0.21 oz) of PETN—"around 50 times less than was used—would be enough to blast a hole in a metal plate twice the thickness of an aircraft's skin".[44] In contrast, according to an experiment conducted by a BBC documentary team designed to simulate Abdulmutallab's Christmas Day bombing, using a Boeing 747 plane, even 80 grams of PETN was not sufficient to materially damage the fuselage.[45]

On 12 July 2017, 150 grams of PETN was found in the Assembly of Uttar Pradesh,[46][47] India's most populous state.[48][49]

Detection

[edit]

In the wake of terrorist PETN bomb plots, an article in Scientific American noted PETN is difficult to detect because it does not readily vaporize into the surrounding air.[42] The Los Angeles Times noted in November 2010 that PETN's low vapor pressure makes it difficult for bomb-sniffing dogs to detect.[20]

Many technologies can be used to detect PETN, including chemical sensors, X-rays, infrared, microwaves[50] and terahertz,[51] some of which have been implemented in public screening applications, primarily for air travel. PETN is one of the explosive chemicals typically of interest in that area, and it belongs to a family of common nitrate-based explosive chemicals which can often be detected by the same tests.

One detection system in use at airports involves analysis of swab samples obtained from passengers and their baggage. Whole-body imaging scanners that use radio-frequency electromagnetic waves, low-intensity X-rays, or T-rays of terahertz frequency that can detect objects hidden under clothing are not widely used because of cost, concerns about the resulting traveler delays, and privacy concerns.[52]

Both parcels in the 2010 cargo plane bomb plot were x-rayed without the bombs being spotted.[53] Qatar Airways said the PETN bomb "could not be detected by x-ray screening or trained sniffer dogs".[54] The Bundeskriminalamt received copies of the Dubai x-rays, and an investigator said German staff would not have identified the bomb either.[53][55] New airport security procedures followed in the U.S., largely to protect against PETN.[20]

Medical use

[edit]

Like nitroglycerin (glyceryl trinitrate) and other nitrates, PETN is also used medically as a vasodilator in the treatment of heart conditions.[4][5] These drugs work by releasing the signaling gas nitric oxide in the body. The heart medicine Lentonitrat is nearly pure PETN.[56]

Monitoring of oral usage of the drug by patients has been performed by determination of plasma levels of several of its hydrolysis products, pentaerythritol dinitrate, pentaerythritol mononitrate and pentaerythritol, in plasma using gas chromatography-mass spectrometry.[57]

See also

[edit]

References

[edit]
  1. ^ "Provisional Peer-Reviewed Toxicity Values for Pentaerythritol Tetranitrate (PETN) (CASRN 78-11-5)" (PDF). United States Environmental Protection Agency. July 2021. Archived (PDF) from the original on August 1, 2024.
  2. ^ "PETN (Pentaerythritol tetranitrate)". Retrieved March 29, 2010.
  3. ^ Childs, John (1994). "Explosives" (Google Books extract). A dictionary of military history and the art of war. ISBN 978-0-631-16848-5.
  4. ^ a b "New Drugs". Can Med Assoc J. 80 (12): 997–998. 1959. PMC 1831125. PMID 20325960.
  5. ^ a b Ebadi, Manuchair S. (1998). CRC desk reference of clinical pharmacology (Google Books excerpt). CRC Press. p. 383. ISBN 978-0-8493-9683-0.
  6. ^ Deutsches Reichspatent 81,664 (1894)
  7. ^ Thieme, Bruno "Process of making nitropentaerythrit," Archived July 11, 2021, at the Wayback Machine U.S. patent no. 541,899 (filed: November 13, 1894; issued: July 2, 1895).
  8. ^ Krehl, Peter O. K. (2009) History of Shock Waves, Explosions and Impact. Berlin, Germany: Springer-Verlag. p. 405.
  9. ^ Urbański, Tadeusz; Ornaf, Władysław and Laverton, Sylvia (1965) Chemistry and Technology of Explosives, vol. 2 (Oxford, England: Permagon Press. p. 175.
  10. ^ German Patent 265,025 (1912)
  11. ^ Stettbacher, Alfred (1933). Die Schiess- und Sprengstoffe (2. völlig umgearb. Aufl. ed.). Leipzig: Barth. p. 459.
  12. ^ Zhurova, Elizabeth A.; Stash, Adam I.; Tsirelson, Vladimir G.; Zhurov, Vladimir V.; Bartashevich, Ekaterina V.; Potemkin, Vladimir A.; Pinkerton, A. Alan (2006). "Atoms-in-Molecules Study of Intra- and Intermolecular Bonding in the Pentaerythritol Tetranitrate Crystal". Journal of the American Chemical Society. 128 (45): 14728–14734. Bibcode:2006JAChS.12814728Z. doi:10.1021/ja0658620. PMID 17090061.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  13. ^ Foltz, M. F. (July 27, 2009). Aging of Pentaerythritol Tetranitrate (PETN) (Technical report). Lawrence Livermore National Laboratory. OSTI 966904. LLNL-TR-415057. Retrieved May 14, 2023.
  14. ^ German, V.N. et al. Thermal decomposition of PENT and HMX over a wide temperature range Archived April 10, 2020, at the Wayback Machine. Institute of Physics of Explosion, RFNC-VNIIEF, Sarov, Russia
  15. ^ Zhuang, Li; Gui, Lai; Gillham, Robert W. (October 1, 2012). "Biodegradation of pentaerythritol tetranitrate (PETN) by anaerobic consortia from a contaminated site". Chemosphere. 89 (7): 810–816. Bibcode:2012Chmsp..89..810Z. doi:10.1016/j.chemosphere.2012.04.062. ISSN 0045-6535. PMID 22647196.
  16. ^ Zhuang, L; Gui, L; Gillham, R. W. (2008). "Degradation of Pentaerythritol Tetranitrate (PETN) by Granular Iron". Environ. Sci. Technol. 42 (12): 4534–9. Bibcode:2008EnST...42.4534Z. doi:10.1021/es7029703. PMID 18605582.
  17. ^ a b Boileau, Jacques; Fauquignon, Claude; Hueber, Bernard & Meyer, Hans H. "Explosives". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a10_143.pub2. ISBN 978-3527306732.
  18. ^ Winslow, Ron. (December 29, 2009) A Primer in PETN – WSJ.com. The Wall Street Journal. Retrieved 2010-02-08.
  19. ^ Oxley, Jimmie C.; Smith, James L.; Kirschenbaum, Louis J.; Shinde, Kajal. P.; Marimganti, Suvarna (2005). "Accumulation of Explosives in Hair". Journal of Forensic Sciences. 50 (4): 826–31. doi:10.1520/JFS2004545. PMID 16078483.
  20. ^ a b c d Bennett, Brian (November 24, 2010). "PETN: The explosive that airport security is targeting". Los Angeles Times. Tribune Washington Bureau. Retrieved July 19, 2015.
  21. ^ a b c Chang, Kenneth (December 27, 2009). "Explosive on Flight 253 Is Among Most Powerful". The New York Times.
  22. ^ "Primacord Technical Information" (PDF). Dyno Nobel. Archived from the original (PDF) on July 10, 2011. Retrieved April 22, 2009.
  23. ^ Zhang, Y.; Li, Q.; He, Y. (2020). "Explosive power of Pentaerythritol Tetranitrate". ACS Omega. 5 (45): 28984–28991. doi:10.1021/acsomega.0c03133. PMC 7675531. PMID 33225129.
  24. ^ PETN (chemical compound). Encyclopædia Britannica. Retrieved February 8, 2010.
  25. ^ Lillian Hoddeson; Paul W. Henriksen; Roger A. Meade; Catherine L. Westfall; Gordon Baym; Richard Hewlett; Alison Kerr; Robert Penneman; Leslie Redman; Robert Seidel (2004). A Technical History of Los Alamos During the Oppenheimer Years, 1943–1945 (Google Books excerpt). Cambridge University Press. pp. 164–173. ISBN 978-0-521-54117-6.
  26. ^ Gebeily, Maya; Pearson, James; Gauthier-Villars, David (October 16, 2024). "How Israel's bulky pager fooled Hezbollah". Reuters. Retrieved October 16, 2024.
  27. ^ Shepodd, T; Behrens, R; Anex, D; Miller, D; Anderson, K (July 1, 1997). Degradation chemistry of PETN and its homologues (Technical report). Sandia National Laboratory. OSTI 650196. SAND-97-8684C. Retrieved May 14, 2023.
  28. ^ Tarzhanov, V. I.; Zinchenko, A. D.; Sdobnov, V. I.; Tokarev, B. B.; Pogrebov, A. I.; Volkova, A. A. (1996). "Laser initiation of PETN". Combustion, Explosion, and Shock Waves. 32 (4): 454. Bibcode:1996CESW...32..454T. doi:10.1007/BF01998499. S2CID 98083192.
  29. ^ US Army – Encyclopedia of Explosives and Related Items, vol.8
  30. ^ Simulation of ram accelerator with PETN layer, Arkadiusz Kobiera and Piotr Wolanski, XXI ICTAM, August 15–21, 2004, Warsaw, Poland
  31. ^ Wei-Guang Liu; et al. (2009). "Explanation of the Colossal Detonation Sensitivity of Silicon Pentaerythritol Tetranitrate (Si-PETN) Explosive" (PDF). J. Am. Chem. Soc. 131 (22): 7490–1. Bibcode:2009JAChS.131.7490L. doi:10.1021/ja809725p. PMID 19489634. Archived from the original (PDF) on March 21, 2018. Retrieved January 3, 2010.
  32. ^ Computational Organic Chemistry » Si-PETN sensitivity explained. Comporgchem.com (July 20, 2009). Retrieved 2010-02-08.
  33. ^ "Article detailing attack on Maison de France in Berlin (German)". Der Spiegel. December 13, 1999. Retrieved November 4, 2010.
  34. ^ "'Shoe bomb suspect 'did not act alone'". BBC News. January 25, 2002. Retrieved April 22, 2009.
  35. ^ "Saudi suicide bomber hid IED in his anal cavity". Homeland Security Newswire. September 9, 2009. Archived from the original on December 31, 2009. Retrieved December 28, 2009.
  36. ^ England, Andrew (November 1, 2010). "Bomb clues point to Yemeni terrorists". Financial Times. Archived from the original on December 10, 2022.
  37. ^ "Saudi Bombmaker Key Suspect in Yemen Plot". CBS News. November 1, 2010. Archived from the original on November 2, 2012. Retrieved November 2, 2010.
  38. ^ "Al Qaeda Claims Responsibility for Attempted Bombing of U.S. Plane". FOX News Network. December 28, 2009. Archived from the original on December 31, 2009. Retrieved December 29, 2009.
  39. ^ "Criminal Complaint" (PDF). The Huffington Post. Archived (PDF) from the original on October 9, 2022. Retrieved November 4, 2010.
  40. ^ "Investigators: Northwest Bomb Plot Planned by al Qaeda in Yemen". ABC News. December 26, 2009. Retrieved December 26, 2009.
  41. ^ Explosive in Detroit terror case could have blown hole in airplane, sources say The Washington Post. Retrieved February 8, 2010.
  42. ^ a b Greenemeier, Larry. "Exposing the Weakest Link: As Airline Passenger Security Tightens, Bombers Target Cargo Holds". Scientific American. Retrieved November 3, 2010.
  43. ^ a b Shane, Scott; Worth, Robert F. (November 1, 2010). "Early Parcels Sent to U.S. Were Eyed as Dry Run". The New York Times.
  44. ^ "Parcel bombs could rip 50 planes in half". India Today. Retrieved November 3, 2010.
  45. ^ "'Underwear Bomber' Could not have Blown Up Plane". Discovery. March 10, 2010. Archived from the original on October 13, 2010. Retrieved November 16, 2010.
  46. ^ "What is PETN explosive device found in Uttar Pradesh Assembly?". July 15, 2017.
  47. ^ "Highly explosive PETN found in Uttar Pradesh Assembly: Yogi Adityanath demands NIA probe". July 14, 2017.
  48. ^ "Population and decadal change by residence : 2011 (PERSONS)" (PDF). Office of the Registrar General & Census Commissioner, India. p. 2. Archived (PDF) from the original on October 9, 2022.
  49. ^ "Statistical Year Book 2015" (PDF). telangana.gov.in. Directorate of Economics and Statistics, Government of Telangana. Archived (PDF) from the original on October 9, 2022. Retrieved March 4, 2019.
  50. ^ Committee on the Review of Existing and Potential Standoff Explosives Detection Techniques, National Research Council (2004) Existing and Potential Standoff Explosives Detection Techniques, National Academies Press, Washington, D.C. p. 77.
  51. ^ Bou-Sleiman, J.; Perraud, J.-B.; Bousquet, B.; Guillet, J.-P.; Palka, N.; Mounaix, P. (2015). "Discrimination and identification of RDX/PETN explosives by chemometrics applied to terahertz time-domain spectral imaging". In Salmon, Neil A; Jacobs, Eddie L (eds.). Millimetre Wave and Terahertz Sensors and Technology VIII. Vol. 9651. p. 965109. doi:10.1117/12.2197442. S2CID 137950290.
  52. ^ "Equipment to detect explosives is available". The Washington Post. Retrieved February 8, 2010.
  53. ^ a b "Foiled Parcel Plot: World Scrambles to Tighten Air Cargo Security". Der Spiegel. Retrieved November 2, 2010.
  54. ^ "Q&A: Air freight bomb plot". BBC News. October 30, 2010. Retrieved November 3, 2010.
  55. ^ "Passenger jets carried Dubai bomb". Al Jazeera. October 31, 2010.
  56. ^ Russek H. I. (1966). "The therapeutic role of coronary vasodilators: glyceryl trinitrate, isosorbide dinitrate, and pentaerythritol tetranitrate". American Journal of the Medical Sciences. 252 (1): 9–20. doi:10.1097/00000441-196607000-00002. PMID 4957459. S2CID 30975527.
  57. ^ Baselt, R. (2008) Disposition of Toxic Drugs and Chemicals in Man, 8th edition, Biomedical Publications, Foster City, CA. pp. 1201–1203. ISBN 0962652369.

Further reading

[edit]
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